An illustration of the limit of the metal organic framework's isoreticular principle using a semirigid tritopic linker obtained by "Click" chemistry

作者：Devic Thomas^*; David Olivier; Valls Marion; Marrot Jerome; Couty Francois; Ferey Gerard

来源：Journal of the American Chemical Society, 2007, 129(42): 12614-+.

DOI：10.1021/ja0744091

A new nitrogen-rich tricarboxylate linker was prepared by "click" chemistry and used for the preparation of a lanthanum-based open metal organic framework. This latter is built of inorganic 1-D rods connected through the tritopic linkers and illustrates one limit of the isoreticular principle, which is related to the partial flexibility of the linkers.

• 出版日期2007-10-24