Non-isothermal kinetics of spin crossover

作者:Bushuev Mark B; Nikolaenkova Elena B; Krivopalov Viktor P
来源:Physical Chemistry Chemical Physics, 2017, 19(26): 16955-16959.
DOI:10.1039/c7cp03442c

摘要

Non-isothermal magnetic studies can be used to estimate the activation energy of cooperative spin transition. Model-free isoconversional integral methods give reliable estimates of the activation barrier height for highly cooperative spin crossover systems with wide thermal hysteresis.

  • 出版日期2017-7-14