Accessing functionalized porous aromatic frameworks (PAFs) through a de novo approach

作者:Garibay Sergio J*; Weston Mitchell H; Mondloch Joseph E; Colon Yamil J; Farha Omar K; Hupp Joseph T; Nguyen SonBinh T
来源:CrystEngComm, 2013, 15(8): 1515-1519.
DOI:10.1039/c2ce26595h

摘要

Methyl-, hydroxymethyl-, and phthalimidomethyl-functionalized versions of the porous organic polymer PAF-1 have been obtained through de novo synthesis. The CO2 adsorption capacity of PAF-1-CH2NH2, obtained through the post-synthesis deprotection of PAF-1-CH2-phthalimide, has been shown to exceed that of PAF-1.