An active core-shell nanoscale design for high voltage cathode of lithium storage devices

作者：Lu, Zhongpei; Liu, Yang; Lu, Xiaojun; Wang, Hao; Yang, Gang^*; Chao, Yimin^*; Li, Weili; Yin, Fan

来源：Journal of Power Sources, 2017, 360: 409-418.

DOI：10.1016/j.jpowsour.2017.06.036

• Li ion batteries
• High volatge cathode material
• Core-shell structure
• LiNi0.5Mn1.5O4

Spinel LiN0.5Mn1.5O4 (LNM) is a potential high-voltage cathode for commercial lithium-ion batteries (LIBs). Maintaining an appropriate amount of Mn3+ in LNM is necessary to improve the rate performance. However, Mn3+ dissolution in the interface of LNM and electrolyte leads to the fast capacity degradation. Therefore, designing a cathode to prevent Mn3+ loss during charge/discharge is important for high performance LIBs. Here we present an active core-shell design with coating another high-voltage cathode material LiCoPO4 (LCP) on the surface of LNM nanoparticles. The LCP layer can simultaneously induce Mn3+ ions at the interface between LCP and LNM, and act as a stable shell to prevent the loss of Mn3+. The optimized sample LNM@5%LCP possesses 128 mAh g(-1) at 0.5 C and 115 mAh g(-1) at 20 C rate, and maintains 96% of the initial capacity operated at 55 degrees C over 100 cycles.

• 出版日期2017-8-31
• 单位江苏科技大学; 常熟理工学院