Assistant template and co-template agents in modeling mesoporous silicas and post-synthesizing organofunctionalizations

作者：Oliveira Vaeudo V; Airoldi Claudio^*

来源：Journal of Solid State Chemistry, 2012, 196: 293-300.

DOI：10.1016/j.jssc.2012.05.042

• SBA-16
• Template
• Co-template
• Functionalization
• Grafting

Mesoporous SBA-16 silicas were synthesized through a direct methodology using the template (F127) combined with co-templates (ethanol and n-butanol), with tetraethylorthosilicate as the silica source. These ordered mesoporous silica were characterized by elemental analyses, infrared spectroscopy, solid-state nuclear magnetic resonance for C-13 (CP/MAS) and Si-29 (HP/DEC) nuclei, nitrogen sorption/desorption processes, small angle X-ray analyses (SAXS) and transmission electron microscopy (TEM). SAXS and TEM results confirmed the space group Im3m and cubic 3D symmetry, typical for highly ordered SBA-16. The sorption/desorption data for SBA-16 and when functionalized gave type IV isotherms, with hysteresis loop H2. Surface areas of 836; 657 and 618 m(2) g(-1) and average pore diameters of 7.99; 8.10 and 9.85 nm, for SBA-16A, SBA-16B and SBA-16C were obtained, respectively. When functionalized the silicas presented a reduction in surface area, pore volume and pore diameter due to the pendant chains that interfere with nitrogen sorption in these measurements. The co-template ethanol favors the ordered mesopores with highest wall thicknesses.

• 出版日期2012-12