A phenalenyl-based neutral stable pi-conjugated polyradical

作者：Yan Weibo; Wan Xiangjian; Xu Yanfei; Lv Xin; Chen Yongsheng^*

来源：Synthetic Metals, 2009, 159(17-18): 1772-1777.

DOI：10.1016/j.synthmet.2009.05.025

• Phenalenyl
• Polyradical
• Conducting polymers
• Electrochemistry
• Disorder

The first neutral pi-conjugated polyradical based on phenalenyl with the spin unit inside the main chain was prepared. Cyclic voltammetry studies showed that this polyradical had excellent redox reversibility and enhanced pi-delocalization between the neighboring spin units, in consistent with the UV-vis results. Initial magnetic studies showed that a strong antiferromagnetic interaction existed at solid state. The conductivity of the polyradical was measured with a value sigma(RT) approximate to 10(-8) S/cm.

• 出版日期2009-9
• 单位南开大学