科研之友
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摘要
We discuss the advantages of a single-valued function (and related formula) for the absolute definition and computation of scattering phase shifts delta(l)(k) in spherically symmetric van der Waals potentials. Although the expression, as such, is known since the 2000s [K. Chadan, R. Kobayashi, and T. Kobayashi, J. Math. Phys. 42, 4031 (2001)], only little numerical evidence of its effectiveness has been available so far. Our effort, here, is to give this device the recognition it deserves and to make it more widely known as an alternative to standard methods. This is all the more interesting as in the standard approaches the access to absolute delta(l)(k) is not straightforward but needs additional operations to be performed. Weshow how the formula can be derived, as a consequence of variable-phase approaches from the two broadly accepted methods for delta(l)(k), and compare its performance with these methods. He-He and two of its keynote thermophysical properties, namely, the He-4 and He-3 second virial and acoustic virial coefficients are being studied for the purpose. The use of absolute delta(l)(k) is mandatory for those coefficients. Other important points related to the concept of phase function delta(l)(k, r) and its connection with Volterra equation are given in Supplementary material.
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- 出版日期2018
