A Rare Tetranuclear Thorium(IV) mu(4)-Oxo Cluster and Dinuclear Thorium(IV) Complex Assembled by Carbon-Oxygen Bond Activation of 1,2-Dimethoxyethane (DME)

作者：Travia Nicholas E; Scott Brian L; Kiplinger Jaqueline L^*

来源：Chemistry - A European Journal, 2014, 20(51): 16846-16852.

DOI：10.1002/chem.201404551

• cluster compounds
• halides
• inorganic synthesis
• water analysis

The synthesis and X-ray crystal structure of two new multinuclear thorium complexes are reported. The tetranuclear m4-oxo cluster complex Th-4(mu(4)-O)(mu-Cl) I-2(6)[k(2)(O, O')-mu-O(CH2)(2)OCH3](6) and the dinuclear complex Th2I5[k(2)(O, O')-mu-O(CH2)(2)OCH3](3)(DME) (DME=dimethoxyethane) are formed by C-O bond activation of 1,2-dimethoxyethane (DME) mediated by thorium iodide complexes.

• 出版日期2014-12-15
• 单位Los Alamos