Seawater-Assisted Self-Healing of Catechol Polymers via Hydrogen Bonding and Coordination Interactions

作者：Li Jincai; Ejima Hirotaka; Yoshie Naoko^*

来源：ACS Applied Materials & Interfaces, 2016, 8(29): 19047-19053.

DOI：10.1021/acsami.6b04075

• bioinspired polymers
• seawater
• catechol
• self-healing metallopolymers

It is highly desirable to prevent crack formation in polymeric materials at an early stage and to extend their lifespan, particularly when repairs to these materials would be difficult for humans. Here, we designed and synthesized catechol-functionalized polymers that can self-heal in seawater through hydrogen bonding and coordination. These bioinspired acrylate polymers are originally viscous materials, but after coordination with environmentally safe, common metal cations in seawater, namely, Ca2+ and Mg2+, the mechanical properties of the polymers were greatly enhanced from viscous to tough, hard materials. Reduced swelling in seawater compared with deionized water owing to the higher osmotic pressure resulted in greater toughness (similar to 5 MPa) and self-healing efficiencies (similar to 80%).

• 出版日期2016-7-27