Dihydrogen phosphate-containing dinuclear double assemblies that demonstrate phosphate reactivity to the tetrafluoroborate anion

作者：Faulkner Robert A; Patmore Nathan J; Rice Craig R^*; Slater Christopher

来源：Chemical Communications, 2018, 54(66): 9159-9162.

DOI：10.1039/c8cc04900a

The ligands L-1 and L-2 both form dinuclear assemblies with Cu(ii) and these react with dihydrogen phosphate so that the anion is incorporated within the assembly (e.g. [Cu2L2(H2PO4)](3+)). However, in the presence of tetrafluoroborate anions the phosphate undergoes reaction with the anion forming [Cu-3(L-1)(3)(O3POBF3)](3+) and [Cu-2(L-2)(2)(O2P(OBF3)(2))](+).

• 出版日期2018-8-25