Diminution of Contact Angle Hysteresis under the Influence of an Oscillating Force

作者：Manor Ofer^*

来源：Langmuir, 2014, 30(23): 6841-6845.

DOI：10.1021/la5006924

We suggest a simple quantitative model for the diminution of contact angle hysteresis under the influence of an oscillatory force invoked by thermal fluctuations, substrate vibrations, acoustic waves, or oscillating electric fields. Employing force balance rather than the usual description of contact angle hysteresis in terms of Gibbs energy, we highlight that a wetting system, such as a sessile drop or a bubble adhered to a solid substrate, appears at long times to be partially or fully independent of contact angle hysteresis and thus independent of static friction forces, as a result of contact line pinning. We verify this theory by studying several well-known experimental observations such as the approach of an arbitrary contact angle toward the Young contact angle and the apparent decrease (or increase) in an advancing (or a receding) contact angle under the influence of an external oscillating force.

• 出版日期2014-6-17