mu(1,1)-azide-bridged ferromagnetic Mn-III dimer with slow relaxation of magnetization

作者:Ge CH; Cui AL; Ni ZH; Jiang YB; Zhang LF; Ribas J; Kou HZ*
来源:Inorganic Chemistry, 2006, 45(13): 4883-4885.
DOI:10.1021/ic060479h

摘要

A new end-on azide-bridged dimeric Mn-III complex has been synthesized by using the tridentate N-isonicotinamidosalicylaidimine ligand. Magnetic studies show that the complex has a high-spin ground state of S = 4 and is ac out-of-phase frequency-dependent.