A comparative study on the dispersion behaviors and surface acid properties of molybdena on CeO2 and ZrO2 (Tet)

作者:Wan Haiqin; Li Dan; Zhu Haiyang; Zhang Yanhua; Doijg Lihui; Hu Yuhai; Liu Bin; Sun Keqin; Dong Lin*; Chen Yi
来源:Journal of Colloid and Interface Science, 2008, 326(1): 28-34.
DOI:10.1016/j.jcis.2008.07.036

摘要

Dispersion of molybdena on CeO2, ZrO2 (Tet), and a mixture of CeO2 and ZrO2 (Tet), was investigated by using laser Raman spectroscopy (LRS), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and temperature programmed reduction (TPR). The results indicate that molybdena is dispersed on both individual oxide Support and mixed oxide Support at the adopted molybdena loadings (0.2 and 0.8 mmol MoG+/100 m(2)) and the Structure of the supported molybdena species is intimate association with its loading amount. Two molybdena species are identified by Raman results, i.e. isolated MoO42- species at 0.2 mmol Mo6+/100 m(2) and polymolybdate species at 0.8 mmol Mo6+/100 m(2). IR spectra of ammonia adsorption prove that isolated MoO42- species are Lewis acid sites on the Mo/Ce and/or Zr samples, and the polymolybdate species are Bronsted acid sites on the Mo/Ce and/or Zr samples. Moreover, a combination of the Raman, IR and TPR results confirms that at 0.2 mmol Mo6+/100 m(2) Ce + Zr, molybdena is preferentially dispersed on the surface of CeO2 when a mixed oxide support (CeO2 and ZrO2) is present, which was explained in term of the difference of the surface basicity between CeO2 and ZrO2 (Tet). Surface structures of the oxide supports were also taken into consideration.