Novel Highly Efficient Cu/HMS Catalyst and Its Application to the Hydrogenation of Dimethyl Oxalate to Ethylene Glycol

作者：Yin Anyuan^*; Guo Xiuying; Dai Weilin; Fan Kangnian

来源：Acta Chimica Sinica, 2009, 67(15): 1731-1736.

• Cu/HMS
• dimethyl oxalate
• ethylene glycol
• catalytic hydrogenation

A series of mesoporous Cu-HMS catalysts prepared under different calcination temperatures were synthesized by a deposition precipitation method. The catalytic reaction was tested via the hydrogenation of dimethyl oxalate (DMO) to ethylene glycol (EG). The 100% DMO conversion and 97% EG selectivity be obtained over the optimized catalyst calcined at 650 degrees C. XRD, BET, H(2)-TPR, N(2)O titration and XPS were used to unveil the intrinsic essence of the catalyst. It was suggested that the dispersion of copper species and the interaction between the copper species and the silica be closely related to the calculation temperature and play a crucial role in the hydrogenation of DMO to EG.

• 出版日期2009-8-14
• 单位复旦大学