A two dimensional microporous metal-organic framework for selective gas separation

作者：Alawisi, Hussah; Li, Bin; Alfooty, Khalid; Wu, Ling; Xiang, Shengchang; Wang, Hailong; Chen, Banglin^*

来源：Inorganic Chemistry Communications, 2014, 50: 106-109.

DOI：10.1016/j.inoche.2014.10.023

• Metal-organic framework
• X-ray crystal structure
• Gas separation
• Gas sorption

A new organic ligand of 1,1'-biphenyl-containing tetra-carboxylic acid (H4BPTT) and its first metal-organic framework [Zn-2(BPTT)(H2O)(2)]center dot(DMF)(4.5n) (1) was designed, synthesized and structurally characterized exhibiting two-dimensional distorted (4,4) topology. The activated la exhibits permanent porosity and moderately high selectivities for CO2/N-2 and CO2/CH4 gas separations at room temperature.

• 出版日期2014-12
• 单位福建师范大学