Macroinitiator Halide Effects in Galactoglucomannan-Mediated Single Electron Transfer-Living Radical Polymerization

作者：Edlund Ulrica; Albertsson Ann Christine^*

来源：Journal of Polymer Science Part A: Polymer Chemistry , 2011, 49(19): 4139-4145.

DOI：10.1002/pola.24855

• graft copolymers
• hemicellulose
• living polymerization
• macroinitiator
• polysaccharides
• single electron transfer-living radical polymerization (SET-LRP)
• single electron transfer (SET)

Chloro (Cl)- and bromo (Br)-functionalized macroinitiators were successfully prepared from the softwood hemicellulose O-acetylated galactoglucomannan (AcGGM) and then explored and evaluated with respect to their ability and efficiency of initiating single electron transfer-living radical polymerization (SET-LRP). Both halogenated species effectively initiate SET-LRP of an acrylate and a methacrylate monomer, respectively, yielding brushlike AcGGM graft copolymers, where the molecular weights are accurately controlled via the monomer:macroinitiator ratio and polymerization time over a broad range: from oligomeric to ultrahigh. The nature of the halogen does not influence the kinetics of polymerization strongly, however, for acrylate graft polymerization, AcGGM-CI gives a somewhat higher rate constant of propagation, while methacrylate grafting proceeds slightly faster when the initiating species is AcGGM-Br. For both monomers, the macroinitiator efficiency is superior in the case of AcGGM-Br.

• 出版日期2011-10-1