[Zn(INO)(2)(DMF)] center dot DMF: A new three-dimensional supramolecular open framework containing one-dimensional channels

作者：Hong J^*

来源：Journal of Molecular Structure, 2006, 783(1-3): 9-12.

DOI：10.1016/j.molstruc.2005.08.013

• crystal structure
• helical chain
• supramolecular network
• channel
• luminescence

A three-dimensional supramolecular compound, [Zn(INO)(2)(DMF)] center dot DMF (1) (INO = isonicotinic acid N-oxide), has been prepared in the DMF solution at room temperature, and characterized by elemental analysis, TG and single crystal X-ray diffraction. The three-dimensional supramolecular open framework of 1 contains rectangular channels with the dimensions of 9.02 X 10.15 angstrom, assembled from one-dimensional helical chains via hydrogen-bonding and pi-pi stacking interactions. Furthermore, compound 1 shows blue photoluminescence at room temperature.

• 出版日期2006-2-6
• 单位吉林师范大学