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摘要
A new mononuclear Fe(III)-catecholate complex, which exhibits an incomplete spin transition without hysteresis, had been synthesized and structurally characterized, Analyzed from the structural characteristics, the tripodal ligand must play the important role in affecting the spin crossover (SCO) behavior. The larger steric strain effect and weak cooperativity existed in the crystal lattice are inclined to favor the incomplete transition.
