A novel 2D non-interpenetrated copper(I) iodide coordination polymer with trans-1,4-diaminocyclohexane

作者：Zhou Wei Xia; Li Jun^*; Xu Wei Xia; Yuan Long Fei; Braga Dario; Maini Lucia; Zhang Feng xing

来源：Inorganica Chimica Acta, 2012, 382: 162-166.

DOI：10.1016/j.ica.2011.12.041

• Copper(I) iodide
• Crystal structure
• Coordination polymer
• Metal-organic framework
• Photoluminescence property

A novel non-interpenetrated 2D coordination polymer [Cu4I4(DACH)(2)](n) bridged by the flexible trans-1,4-diaminocyclohexane (DACH) ligand has been synthesized under hydrothermal condition and characterized by single crystal X-ray diffraction, TG-DTA and the solid-state luminescence spectrum. In the compound, each Cu4I4 cluster is bridged by DACH ligand to form a quadrate-grid 2D network with the inner cavities of approximate size of 6.35 x 18.12 angstrom. It is unusual that these 2D networks are stacked and there exist the N-H center dot center dot center dot I hydrogen bonds between layers. The channels are finally formed along b-axis with small size of cavities. Thermal analysis shows that the complex is stable up to ca. 240 degrees C. The solid-state luminescence spectrum displays a strong yellow emission band at room temperature, characteristic of the Cu4I4 cluster centers.

• 出版日期2012-3-15
• 单位西北大学