Analytically useful blue chemiluminescence from a water-soluble iridium(III) complex containing a tetraethylene glycol functionalised triazolylpyridine ligand

作者：Smith Zoe M; Kerr Emily; Doeven Egan H; Connell Timothy U; Barnett Neil W; Donnelly Paul S; Haswell Stephen J; Francis Paul S

来源：Analyst, 2016, 141(7): 2140-2144.

DOI：10.1039/c6an00141f

We examine [Ir(df-ppy)(2)(pt-TEG)](+) as the first highly water soluble, blue-luminescent iridium(III) complex for chemiluminescence detection. Marked differences in selectivity were observed between the new complex and the conventional [Ru(bpy)(3)](2+) reagent, which will enable this mode of detection to be extended to new areas of application.

• 出版日期2016