Antiferromagnetic Transition in a Novel Star-shaped High-spin Fe(III) Tetranuclear Cluster from a Mononuclear Coordination Anion Featuring pi-Extended Schiff Base Ligands

作者：Takahashi Kazuyuki^*; Kawamukai Kiko; Mochida Tomoyuki; Sakurai Takahiro; Ohta Hitoshi; Yamamoto Takashi; Einaga Yasuaki; Mori Hatsumi; Shimura Yasuyuki; Sakakibara Toshiro; Fujisawa Takumi; Yamaguchi Akira; Sumiyama Akihiko

来源：Chemistry Letters, 2015, 44(6): 840-842.

DOI：10.1246/cl.150196

A novel star-shaped high-spin Fe(III) tetranuclear cluster was unexpectedly obtained by the reaction of an [Fe-III(phsal)(2)](-) anion with an Fe(III) coordination cation (H(2)phsal: N-(2-hydroxyphenyl)salicylaldimine). Despite a star-shaped Fe(III) tetranuclear structure similar to reported Fe(III) single molecule magnets, the present compound exhibited a bulk antiferromagnetic transition at 0.6 K due to a magnetic exchange coupling through intercluster pi-stacking interactions.

• 出版日期2015-6-5