Nickel-Catalyzed Alkenylative Cross-Coupling Reaction of Alkyl Sulfides

作者:Ishizuka Kentaro; Seike Hirofumi; Hatakeyama Takuji; Nakamura Masaharu*
来源:Journal of the American Chemical Society, 2010, 132(38): 13117-13119.
DOI:10.1021/ja104155f

摘要

A novel cross-coupling reaction of alkyl aryl sulfides with aryl Grignard reagents has been achieved to produce the alkenyl-aryl coupling products in high yields by using catalytic Ni(cod)(2) and a bulky N-heterocyclic carbene ligand, SIPr.

  • 出版日期2010-9-29