Efficient H-2 generation from formic acid using azole complexes in water

作者：Manaka Yuichi^*; Wang Wan Hui; Suna Yuki; Kambayashi Hide; Muckerman James T; Fujita Etsuko; Himeda Yuichiro

来源：Catalysis Science & Technology, 2014, 4(1): 34-37.

DOI：10.1039/c3cy00830d

Iridium azole-containing complexes are demonstrated to catalyze the dehydrogenation of formic acid into H-2-CO2 (1/1) mixtures in aqueous solution in the absence of organic additives, and with a maximum turnover frequency (TOF) of 34000 h(-1) at 80 degrees C.

• 出版日期2014