Diaquabis[2-(benzyloxy)acetato]-cobalt(II)

作者:Chen, Chun-Liang; Sun, Sheng-Li; Gu, Chang-Sheng*; Song, Weng-Dong; Hao, Xiao-Min
来源:ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2008, 64: M890-U344.
DOI:10.1107/S1600536808016899

摘要

In the mononuclear title complex, [Co(C9H9O3)(2)(H2O)(2)], each Co-II atom is located on an inversion center and is hexacoordinated by four O atoms from two benzyloxyacetate ligands [Co-O bond lengths = 2.0487 (9) and 2.1090 (9) angstrom] and two water molecules [Co-O bond length = 2.0873 (9) angstrom] in a distorted octahedral geometry. In the crystal structure, intermolecular hydrogen bonds and pi-pi stacking interactions [centroid-centroid distance between phenyl rings = 3.692 (2) angstrom] link the molecules into a supramolecular structure.