Depletion effects in colloid-polymer solutions

作者：D' Adamo Giuseppe; Pelissetto Andrea; Pierleoni Carlo^*

来源：Molecular Physics, 2013, 111(22-23): 3372-3393.

DOI：10.1080/00268976.2013.836255

• polymer physics
• colloids
• statistical mechanics of interfaces
• Monte Carlo

The surface tension, the adsorption, and the depletion thickness of polymers close to a single non-adsorbing colloidal sphere are computed by means of Monte Carlo simulations. We consider polymers under good-solvent conditions and in the thermal crossover region between the good solvent and behaviour. In the dilute regime, we consider a wide range of values of q, from q = 0 (planar surface) up to q approximate to 30-50, while in the semidilute regime, for (p)(p) 4 ((p) is the polymer concentration and *(p) is its value at overlap), we only consider q = 0, 0.5, 1 and 2. The results are compared with the available theoretical predictions, verifying the existing scaling arguments. Field-theoretical results, both in the dilute and in the semidilute regime, are in good agreement with the numerical estimates for polymers under good-solvent conditions.

• 出版日期2013-12-1