Dinuclear neodymium(III) complex cationic {12[ane]HN4(CH2C equivalent to CH)(4)}(+) with sensitized near-infrared luminescence by ion-association sensitizer

作者：Xu, Hai-Bing^*; Chao, Hsiu-Yi

来源：Inorganic Chemistry Communications, 2007, 10(10): 1129-1131.

DOI：10.1016/j.inoche.2007.06.015

• N,N',N '',N '''-tetra-(3-prop-1-yne)-1,4,7,10-tetrazacyclododecane
• luminescence
• neodymium
• hexafluoroacetylacetonate

A new complex Nd-2(hfac)(6)(CH3COO)(2) {12[ane]HN4(CH2C CH)(4)}(2) (hexafluoroacetylacetonate, hfac) was synthesized and characterized. Upon excitation of the organic cation {12[ane]N4H(CH2C CH)(4)}(+) (protonation on one of the nitrogen atoms of N,N',N',N'''-tetra-(3 -prop-l-yne)- 1,4,7,10-tetrazacycl ododecane), the neodymium NIR luminescence is sensitized through Forster energy transfer mechanism.

• 出版日期2007-10
• 单位中山大学