Novel Iron-based ternary amorphous oxide semiconductor with very high transparency, electronic conductivity, and mobility

作者：Malasi A; Taz H; Farah A; Patel M; Lawrie B; Pooser R; Baddorf A; Duscher G; Kalyanaraman R^*

来源：Scientific Reports, 2015, 5(1): 18157.

DOI：10.1038/srep18157

Here we report that ternary metal oxides of type (Me)(2)O-3 with the primary metal (Me) constituent being Fe (66 atomic (at.) %) along with the two Lanthanide elements Tb (10 at.%) and Dy (24 at.%) can show excellent semiconducting transport properties. Thin films prepared by pulsed laser deposition at room temperature followed by ambient oxidation showed very high electronic conductivity (>5 x 10(4) S/m) and Hall mobility (>30 cm(2)/V-s). These films had an amorphous microstructure which was stable to at least 500 degrees C and large optical transparency with a direct band gap of 2.85 +/- 0.14 eV. This material shows emergent semiconducting behavior with significantly higher conductivity and mobility than the constituent insulating oxides. Since these results demonstrate a new way to modify the behaviors of transition metal oxides made from unfilled d- and/or f-subshells, a new class of functional transparent conducting oxide materials could be envisioned.

• 出版日期2015-12-16