A convergent approach for the total synthesis of the alpha-glucosidase inhibitor (-)-panaxjapyne-C

作者:Reddy A Sathish; Gangadhar P; Srihari P*
来源:Tetrahedron: Asymmetry , 2013, 24(23): 1524-1530.
DOI:10.1016/j.tetasy.2013.09.017

摘要

The stereoselective total synthesis of (-)-panaxjapyne-C was accomplished in a convergent fashion. The synthesis utilizes the readily available enantiomers L-(+)-diethyltartrate and D-(-)-diethyltartrate and involves a Cadiot-Chodkiewicz coupling reaction, and an Ohira-Bestmann reaction as the key steps.

  • 出版日期2013-12-15