A nona-vacant Keggin-type tricarbonyl rhenium derivative {[PMo3O16][Re(Co)(3)](4)}(5-) and its catalytic performance for CO2 cycloaddition reactionst

作者：Huo Zhiyuan; Guo Jipeng; Lu Jingkun; Xu Qiaofei; Ma Pengtao; Zhao Juan; Zhang Dongdi; Niu Jingyang^*; Wang Jingping

来源：RSC Advances, 2015, 5(84): 69006-69009.

DOI：10.1039/c5ra14201f

A nona-vacant Keggin-type tricarbonyl rhenium derivative [(NH4)(5)] ([PMo3O16][Re(CO)(3)](4)} 1.5H(2)O was obtained and characterized. Its frontier orbitals were computed by density functional theory (DFT) calculations. Furthermore, it could act as a Lewis acid catalyst and promote the conversion of CO2 to cyclic carbonate under mild reaction conditions with pyrrolidinium bromide as a co-catalyst.

• 出版日期2015
• 单位河南大学