Direct Asymmetric Benzoyloxylation of Aldehydes Catalyzed by 2-Tritylpyrrolidine

作者：Kano Taichi; Mii Haruka; Maruoka Keiji^*

来源：Journal of the American Chemical Society, 2009, 131(10): 3450-+.

DOI：10.1021/ja809963s

A direct asymmetric benzoyloxylation of aldehydes with benzoyl peroxide was found to be catalyzed by (S)-2-(triarylmethyl)pyrrolidines (S)-2. This method provides a new approach for the preparation of optically active alpha-benzoyloxyaldehydes as useful chiral building blocks.

• 出版日期2009-3-18