Detection of the Heterochirality of a 1:2 Metal/Ph-pybox Complex Ion by ESIMS

作者：Sato Hirofumi^*; Suzuki Yoshitomo; Takai Yoshio; Kawasaki Hideya; Arakawa Ryuichi; Shizuma Motohiro

来源：Chemistry Letters, 2010, 39(6): 564-566.

DOI：10.1246/cl.2010.564

The heterochirality of a 1:2 metal/Ph-pybox complex ion was encyclopedically evaluated by ESIMS using pseudo-racemic (R,R)- and (S,S)-Ph-pybox pair, which were unlabeled/labeled by deuterium atoms, respectively. The heterochiral complex was predominantly formed in all investigated 1:2 metal/Ph-pybox complex ions.

• 出版日期2010-6-5