A comparative investigation on the low-temperature catalytic oxidation of acetone over porous aluminosilicate-supported cerium oxides

作者：Lin Liang Yi; Wang ChenYeh; Bai Hsunling^*

来源：Chemical Engineering Journal, 2015, 264: 835-844.

DOI：10.1016/j.cej.2014.12.042

• VOCs oxidation
• Cerium oxide
• Mesoporous silica
• ZSM-5
• Aerosol flow

The performance of cerium oxide supported on mesoporous aluminosilicate particles (Al-MSPs) with a nominal Ce and Al loading of 2.8 and 1.2 wt.%, respectively, was evaluated for the low-temperature oxidation of acetone. The influence of the preparation methods, including one-step aerosol-assisted self-assembly (AASA) method and post-synthetic wet impregnation method, was examined. The results showed that the surface area and pore diameter of Ce/Al-MSPs(50/25) prepared by AASA method were similar to those of Ce-Al-MSPs made via traditional impregnation method, while a better metallic dispersion of Ce and Al oxide species on Ce/Al-MSP5(50/25) was observed as compared to that of Ce-Al-MSPs. The catalytic performances of Ce/Al-MSPs(50/25) and Ce-Al-MSPs were compared with that of cerium-impregnated H-ZSM-5 (Ce-ZSM-5) zeolite catalyst. The activity of freshly made catalysts followed the order: Ce/Al-MSPs(50/25) > Ce-ZSM-5 > Ce-Al-MSPs. The superior catalytic behavior of the Ce/Al-MSPs(50/25) could be due to the combined effect of strong surface reducibility and high acid property. Although Ce-ZSM-5 and Ce-Al-MSPs presented high activity for acetone removal in the beginning, their activities quickly decreased due to the coking effect. In contrast, Ce/Al-MSP5(50/25) showed a good stability during a 24 h test at the reaction temperature of 150 degrees C. Both surface reducibility and acidity played crucial roles for their high catalytic performance and high stability at low temperatures.

• 出版日期2015-3-15