A novel 2D (4,4) cobalt(II)-organic framework based on tetranuclear cluster nodes and double stranded organic linkers

作者：Zhou, Yan; Han, Lei^*; Pan, Jianguo; Li, Xing; Zheng, Yueqing

来源：Inorganic Chemistry Communications, 2008, 11(10): 1107-1109.

DOI：10.1016/j.inoche.2008.06.008

• Metal-organic frameworks
• Cobalt(II)
• Tetranuclear clusters
• 4,4 '-(Hexafluoroisopropylidene)bis(benzoic acid)

A novel 2D cobalt(II)-organic framework, [Co2(mu(2)-H2O)(hfipbb)(2)(py)(3)] center dot 2(py)](n) (1) (H(2)hfipbb = 4,4'-(hexafluoroisopropylidene)bis(benzoic acid), py = pyridine), has been synthesized under hydrothermal reaction. Single-crystal X-ray diffraction revealed that I is a noninterpenetration (4,4) network based on unique tetranuclear clusters and double stranded organic linkers. The powder X-ray diffraction and thermogravimetric analysis of I have also been investigated.

• 出版日期2008-10
• 单位宁波大学