Atom-economic transformations of propargylic alcohols catalyzed by the 16-electron allyl-ruthenium(II) complex [Ru(eta(3)-2-C3H4Me)(CO)(dppf)][SbF6] (dppf=1,1 '-bis(diphenylphosphino)ferrocene)

作者：Cadierno Victorio^*; Garcia Garrido Sergio E; Gimeno Jose; Nebra Noel

来源：Inorganica Chimica Acta, 2010, 363(9): 1912-1934.

DOI：10.1016/j.ica.2009.05.010

• Ruthenium
• Propargylic alcohols
• Allenylidene ligands
• Propargylic substitution
• Isomerization
• Homogeneous catalysis
• Tandem reactions

Recent research work on the catalytic activity of the 16-electron ruthenium(II) complex [Ru(eta(3)-2-C3H4Me)(CO)(dppf)][SbF6] in the isomerization as well as novel carbon-carbon and carbon-heteroatom bond forming reactions using propargylic alcohols as raw materials is reviewed from the viewpoint of organic synthesis. Tandem processes based on these reactions are also included.

• 出版日期2010-6-10