Deposition of N-Al Co-doping p-type ZnO by ultrasonic spray pyrolysis

作者:Fan Hong Bing*; Zhang Xiao Dan; Zhao Ying; Sun Jian; Wei Chang Chun; Wang Rui; Zhang Cun Shan
来源:Journal of Synthetic Crystals, 2006, 35(6): 1332-1336.

摘要

P-type ZnO thin films were synthesized by ultrasonic spray pyrolysis. Effect of solution concentration ratio on the electrical and structural characteristics of thin films was investigated. The result of X-ray diffraction reveals that co-doping ZnO thin films have similar crystallization characteristic like that of un-doping. The results of Hall measurement indicate that conductive type of as-grown ZnO thin films changed from n type to p type and then n type again with the increasing of ratio of N:Al. Using this method p type ZnO thin films was deposited on glass substrate, of which hole concentration is 4.6 × 1018 cm-3, Hall mobility and resistivity are 0.4 cm2·V-1·s-1, 3.3Ω·cm, respectively.

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