A single chain magnet involving hexacyanoosmate

作者：Peresypkina Eugenia V; Majcher Anna M; Rams Michal^*; Vostrikova Kira E

来源：Chemical communications, 2014, 50(54): 7150-7153.

DOI：10.1039/c3cc48972h

The first single chain magnet (SCM) based on orbitally degenerate hexacyanoosmate(III) was prepared. The high values of energy barriers for the [Mn(acacen)Os(CN)(6)](2-) complex of 81 and 48.4 K are the result of interplay of three axes anisotropic coupling of [Os(CN)(6)](3-) with zero field splitted Mn3+.