A simple and efficient PTT-mediated synthesis of alpha-azidoketones in [bmim][BF4] ionic liquid

作者：Kumar Anil^*; Ahmed Israr; Rao M Sudershan; Patel Gautam; Kumar Dalip

来源：Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry , 2009, 48(4): 611-616.

• Phenyltrimethylammonium tribromide (PTT)
• alpha-azidoketones
• ionic liquid

A simple and efficient one-pot method has been described for the direct synthesis of alpha-azidoketones from various ketones possessing alpha-hydrogen by reaction with Phenyltrimethylammonium tribromide (FIT) and subsequent treatment with NaN3 in ionic liquid. The procedure gives high yield and the ionic liquid can be resued.

• 出版日期2009-4