Association and Solvation of Silver Nitrate and Perchlorate in Aqueous Ethanol

作者：Gamov G A^*; Zavalishin M N; Novikov I V; Dushina S V; Sharnin V A

来源：Journal of Solution Chemistry, 2016, 45(2): 286-298.

DOI：10.1007/s10953-016-0436-3

• Dissociation constant
• Gibbs energy
• Silver nitrate
• Silver perchlorate
• Conductivity
• Conductometry

The molar conductivities of silver nitrate and perchlorate solutions in aqueous ethanol (X (EtOH) = 0.5-0.9 and X (EtOH) = 0.9, respectively) were measured. Using the conductometry data, the values of dissociation constants and limiting conductivities (lambda (0)) of these electrolytes were calculated. The results were discussed by employing a solvation-thermodynamic approach. The hydrodynamic radii of Ag+, and ions were estimated.

• 出版日期2016-2