A Structural Molar Volume Model for Oxide Melts Part III: Fe Oxide-Containing Melts

作者：Thibodeau Eric; Gheribi Aimen E; Jung In Ho^*

来源：Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science, 2016, 47(2): 1187-1202.

DOI：10.1007/s11663-015-0549-x

As part III of this series, the model is extended to iron oxide-containing melts. All available experimental data in the FeO-Fe2O3-Na2O-K2O-MgO-CaO-MnO-Al2O3-SiO2 system were critically evaluated based on the experimental condition. The variations of FeO and Fe2O3 in the melts were taken into account by using FactSage to calculate the Fe2+/Fe3+ distribution. The molar volume model with unary and binary model parameters can be used to predict the molar volume of the molten oxide of the Li2O-Na2O-K2O-MgO-CaO-MnO-PbO-FeO-Fe2O3-Al2O3-SiO2 system in the entire range of compositions, temperatures, and oxygen partial pressures from Fe saturation to 1 atm pressure.

• 出版日期2016-4
• 单位McGill