Aquabis(4-chloro-2-hydroxybenzoato-kappa O)(1,10-phenanthroline-kappa N-2,N ')zinc(II)

作者：Nie Jing Jing; Xu Xun; Xu Duan Jun^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2011, 67: M855-U407.

DOI：10.1107/S1600536811020435

In the title compound, [Zn(C7H4ClO3)(2)(C12H8N2)(H2O)], the Zn-II cation is coordinated by two 4-chloro-2-salicylate anions, one 1,10-phenanthroline ligand and one water molecule in a square-pyramidal coordination geometry; the Zn cation lies 0.4591 (11) angstrom from the basal plane. The benzene rings of the anions are involved in pi-pi stacking. The centroid-centroid distance between parallel benzene rings of adjacent molecules is 3.9017 (17) angstrom, and the centroid-centroid distance between benzene and pyridine rings of adjacent molecules is 3.584 (2) angstrom. Intramolecular O-H center dot center dot center dot O hydrogen bonding is present.

• 出版日期2011-7
• 单位浙江大学