N,N-Di- and N,N,C-Trialkylation of alpha-Sulfoximino Esters

作者：Hata Shingo; Maeda Tatsuya; Shimizu Makoto^*

来源：Bulletin of the Chemical Society of Japan, 2012, 85(11): 1203-1205.

DOI：10.1246/bcsj.20120195

N,N-Dialkylation of alpha-sulfoximino esters with Grignard reagents proceeds to give alpha-N,N-dialkylamino esters. N,N,C-Trialkylated product is also obtained via the oxidation and nueleophilic addition reaction of the intermediary enolate.

• 出版日期2012-11-15