All-optical structure assignment of individual single-walled carbon nanotubes from Rayleigh and Raman scattering measurements

作者：Berciaud Stephane^*; Deshpande Vikram V; Caldwell Robert; Miyauchi Yuhei; Voisin Christophe; Kim Philip; Hone James; Heinz Tony F

来源：Physica Status Solidi B-Basic Solid State Physics, 2012, 249(12): 2436-2441.

DOI：10.1002/pssb.201200152

• carbon nanotubes
• excitons
• Raman scattering
• Rayleigh scattering

We present an all-optical method for structure assignment of individual single-walled carbon nanotubes (SWNTs) based on combined measurements of the elastically (Rayleigh) and inelastically (Raman) scattered light by individual freestanding specimens. The optical resonances of a single SWNT are identified from the Rayleigh spectra. These measurements are complemented with an independent estimation of the SWNT diameter and chiral angle from its radial breathing and G Raman modes, respectively. An assignment of the (n,m) chiral indices can thus be provided. In the most simple cases, a reliable structure assignment can be inferred from the Rayleigh spectra alone. However, we also show that SWNTs with different structures may display similar Rayleigh spectra within a given photon energy In these situations, Raman measurements provide unambiguous criteria for a proper structure assignment. This approach is particularly helpful in order to identify the high-symmetry armchair and zig-zag structures.

• 出版日期2012-12