Diamondoid architectures from halogen-bonded halides

作者:Gunawardana C A; Dakovic M; Aakeroy C B*
来源:Chemical Communications, 2018, 54(6): 607-610.
DOI:10.1039/c7cc08839f

摘要

The reactions between a tetrahedrally-shaped tecton, tetrakis-(4-(iodoethynyl)phenyl)methane, and tetraphenylphosphonium halides readily afford interpenetrated and densely packed diamondoid architectures sustained by C-I ... X- (X- = chloride, bromide, iodide) interactions. In all these halogen-bonded networks, the halide anions act as four-connecting nodes, while the tetraphenylphosphonium cations provide essential templating information and structural support.

  • 出版日期2018-1-18