Alkylation of chlorin p(6) N-hydroxycycloimide with the use of 1,8-diazabicyclo[5.4.0]undec-7-ene

作者:Lebedeva Viktoriya S*; Karmova Fatima M; Mironov Andrey F
来源:Mendeleev Communications, 2015, 25(2): 117-118.
DOI:10.1016/j.mencom.2015.03.012

摘要

The hydroxyl group of N-hydroxycycloimide in a chlorin macrocycle is easily alkylated with haloalkanes in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene to give chlorin p(6) N-alkoxycycloimides in yields to 80%.

  • 出版日期2015-4