A solvothermal and mechanochemical strategy for the construction of chiral N,N-ditopic metalloligands: oxygenation process of a Cu(I)X/quinine system

作者：Prochowicz Daniel; Justyniak Iwona; Kornowicz Arkadiusz; Komorski Szymon; Lewinsski Janusz^*

来源：Inorganic Chemistry Communications, 2014, 46: 216-218.

DOI：10.1016/j.inoche.2014.06.002

• Mechanochemistry
• Metalloligand
• Copper
• Oxygenation
• Cinchona alkaloid

Oxygenation process of a CuX/QN system (where X = Cl, Br; QN-H = quinine) involving either a solvothermal or mechanochemical approach affords novel chiral N,N-ditopic metalloligands [XCu(mu-QN)](2). The molecular and crystal structures of the resulting complexes have been determined by single-crystal X-ray diffraction and PXRD.

• 出版日期2014-8