An expanded MIL-53-type coordination polymer with a reactive pendant ligand

作者:Kunicki Hannah; Chamberlain Thomas W; Clarkson Guy J; Kashtiban Reza J; Hooper Joseph E; Dawson Daniel M; Ashbrook Sharon E; Walton Richard I*
来源:CrystEngComm, 2018, 20(31): 4355-4358.
DOI:10.1039/c8ce00891d

摘要

A coordination polymer with a structure isoreticular to MIL-53, but containing a divalent metal cation (Co2+ or Mg2+) and a coordinating 4-styrylpyridine-N-oxide ligand, crystallises under solvothermal conditions; the pendant ligand can be brominated, with evidence from powder X-ray diffraction, element mapping and Br-81 solid-state NMR for this post-synthesis modification.

  • 出版日期2018-8-21