Upconversion Luminescence of Er3+-Doped Yttrium-Stabilized Zirconia Powders

作者：Xu Bin; Zhou Yong qiang^*; Wang He; Cao Li li

来源：Spectroscopy and Spectral Analysis, 2014, 34(12): 3214-3217.

DOI：10.3964/j.issn.1000-0593(2014)12-3214-04

• Erbium
• Chemical coprecipitation
• Upconversion
• Yttrium stabilized zirconia
• Cross relaxation

Er3+-doped yttrium-stabilized zirconia upconversion powders Zr0.92-x Y-0.08 O1.96-0.5x : xEr(3+) (x = 0. 001 similar to 0. 11) were synthesized via chemical coprecipitation method at 1 200 degrees C for 3 hours. Phase structure and upconversion luminescence spectra of the samples were characterized by X-ray diffractometer and fluorescence spectrometer, respectively. The proposed upconversion mechanism of the samples was discussed. The results indicate that good crystallinity cubic ZrO2 solid solution can be stabilized by introducing 8 mol% yttrium ions. Size and valent differences between trivalent Y3+ and quadrivalent Zr4+ ions generate asymmetry and oxygen vacancies, which contribute to the stability of upconversion luminescence properties and luminescence intensity increase of the samples, and expand its practical application fields. Under 980nm excitation, the samples emit green light centered at 539 nm(H-2(11/2) -> I-4(15/2)) 552 nm(S-4(3/2) -> I-4(15/2)) and red light at 656 and 680 nm (F-4(9/2) -> I-15/2). When Er3+ doping concentration (0.1 mol%) is low, the main green emission of samples is ascribed to the excited state absorption (ESA) processes; With the Er3+ concentration increases from 0. 1% to 11 mol%, there exist three cross relaxation (CR) processes: H-2(11/2)+ I-4(15/2) -> I-4(9/2) + I-4(i3/2), F-4(7/2) + I-4(.11/2) -> 2 F-4(9/2) and I-4(15/2) + I-4(9/2) -> 2 I-4(13/2), causing that the red emissions increase markedly whereas the green emissions decrease. When Er3+ doping concentration(9 mol%) is high, the sample mainly presents red luminescence due to the dominated CR processes in upconversion process.

• 出版日期2014-12
• 单位温州大学