An unprecedented (6,8)-connected self-penetrating network based on two distinct zinc clusters

作者:Lan Ya Qian; Wang Xin Long; Li Shun Li; Su Zhong Min*; Shao Kui Zhan; Wang En Bo
来源:Chemical Communications, 2007, (46): 4863-4865.
DOI:10.1039/b709835a

摘要

The first (6,8)-connected self-penetrating metal-organic framework has been constructed using an asymmetric neutral ligand based on dinuclear zinc clusters, as six-connected nodes, and trinuclear zinc clusters as eight-connected nodes, representing the highest-connected binodal network topology presently known for self-penetrating systems.