A readily available urea based MOF that act as a highly active heterogeneous catalyst for Friedel-Crafts reaction of indoles and nitrostryenes

作者：Zhu, Chengfeng^*; Mao, Qingqing; Li, De; Li, Changda; Zhou, Yiyang; Wu, Xiang; Luo, Yunfei^*; Li, Yougui

来源：Catalysis Communications, 2018, 104: 123-127.

DOI：10.1016/j.catcom.2017.10.010

• Heterogeneous catalysis
• Metal organic frameworks based catalysts
• Hydrogen-bond-donating catalyst
• Urea

A new urea-containing metal-organic framework has been rationally synthesized from a V-shaped dicarboxylate ligand and utilized as hydrogen-bond-donating catalyst, which is highly efficient and recyclable for Friedel-Crafts reaction. The MOF catalyst has the advantages of excellent product yields and a low catalyst loading. Moreover, the catalyst shows a remarkably superior activity compared to its homogenous urea counterparts.

• 出版日期2018-1-10
• 单位合肥工业大学