科研之友
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摘要
With the increasing interest in two-dimensional van der Waals materials, molybdenum disulfide (MoS2) has emerged as a promising material for electronic and energy storage devices. It suffers from poor cycling stability and Low rate capability when used as an anode in Lithium ion batteries. Here, N-doped MoS2 nanosheets with 2-8 atomic Layers, increased interlayer distance, mesoporous structure and high surface area synthesised by a simple soL-geL method show an enhanced Lithium storage performance, delivering a high reversible capacity (998.0 mA h g(-1), 50 mA g(-1)), high rate performance (610 mA h g-1, 2 A g(-1)), and excellent cycling stability. The excellent Lithium storage performance of the MoS2 nanosheets might be due to the better electrical and ionic conductivity and improved Lithium ion diffusion which are related to their structural characteristics and high concentration N doping. The possible mechanism of the improved performance is proposed and discussed.
- 出版日期2016
